KEGG:R00014

2-oxoglutarate dehydrogenase complex: pyruvate dehydrogenase (see R01699), subsequently R03270

pyruvate:thiamin diphosphate acetaldehydetransferase (decarboxylating)

Pyruvate[C3H4O3] + Thiamin diphosphate[C12H19N4O7P2S] = 2-(alpha-Hydroxyethyl)thiamine diphosphate[C14H23N4O8P2S] + CO2[CO2]

DB Links

Alias

Metabolites

Substrates
metabolite compartment Structure
Pyruvate

Formula: C3H4O3
Cytoplasm
Thiamin diphosphate

Formula: C12H19N4O7P2S
Cytoplasm
Products
metabolite compartment Structure
2-(alpha-Hydroxyethyl)thiamine diphosphate

Formula: C14H23N4O8P2S
Cytoplasm
CO2

Formula: CO2
Cytoplasm