Hydrogen

Hydrogen is a colorless, odorless, nonmetallic, tasteless, highly flammable diatomic gas with the molecular formula H2. With an atomic weight of 1.00794, hydrogen is the lightest element. Besides the common H1 isotope, hydrogen exists as the stable isotope Deuterium and the unstable, radioactive isotope Tritium. Hydrogen is the most abundant of the chemical elements, constituting roughly 75% of the universe's elemental mass. Hydrogen can form compounds with most elements and is present in water and most organic compounds. It plays a particularly important role in acid-base chemistry, in which many reactions involve the exchange of protons between soluble molecules. Oxidation of hydrogen, in the sense of removing its electron, formally gives H+, containing no electrons and a nucleus which is usually composed of one proton. That is why H+ is often called a proton. This species is central to discussion of acids. Under the Bronsted-Lowry theory, acids are proton donors, while bases are proton acceptors. A bare proton H+ cannot exist in solution because of its strong tendency to attach itself to atoms or molecules with electrons. However, the term 'proton' is used loosely to refer to positively charged or cationic hydrogen, denoted H+. H2 is a product of some types of anaerobic metabolism and is produced by several microorganisms, usually via reactions catalyzed by iron- or nickel-containing enzymes called hydrogenases. These enzymes catalyze the reversible redox reaction between H2 and its component two protons and two electrons. Creation of hydrogen gas occurs in the transfer of reducing equivalents produced during pyruvate fermentation to water. Hydrogen has been found to be a metabolite of Citrobacter, Cyanobacteria, Enterobacter, Halobacterium and Rhodobacteraceae (PMID: 28042989; PMID: 16371161) (https://www.insa.nic.in/writereaddata/UpLoadedFiles/PINSA/Vol51B_1985_2_Art16.pdf) (https://www.researchgate.net/publication/222428793_High_Hydrogen_Yield_from_a_Two-step_Process_of_Dark-_and_Photo-fermentation_of_Sucrose) (Tao, Y; Chen, Y; Wu, Y; He, Y; Zhou, Z (2007). "High hydrogen yield from a two-step process of dark- and photo-fermentation of sucrose". International Journal of Hydrogen Energy. 32 (2): 200-206).

ID EC Number Name
KEGG:R00019 1.12.7.2 hydrogen:ferredoxin oxidoreductase;
KEGG:R00067 1.18.6.1 reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
KEGG:R00700 1.12.1.2 hydrogen:NAD+ oxidoreductase
KEGG:R02965 1.12.5.1 hydrogen:quinone oxidoreductase
KEGG:R03025 1.12.98.1 hydrogen:coenzyme F420 oxidoreductase
KEGG:R04015 1.12.2.1 hydrogen:ferricytochrome-c3 oxidoreductase
KEGG:R04455 1.12.98.2 hydrogen:N5,N10-methenyltetraydromethanopterin oxidoreductase
KEGG:R05185 1.18.6.1 reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
KEGG:R05186 1.19.6.1 reduced flavodoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
KEGG:R07181 1.12.1.3 hydrogen:NADP+ oxidoreductase
KEGG:R07182 1.12.99.6 hydrogen:(acceptor) oxidoreductase
KEGG:R09095 1.12.2.- hydrogen:2-(2,3-dihydropentaprenyloxy)phenazine oxidoreductase
KEGG:R09508 1.12.1.4 hydrogen:NAD+, ferredoxin oxidoreductase
KEGG:R10390 1.12.98.4 H2:polysulfide oxidoreductase
KEGG:R11943 1.8.98.5 CoB,CoM,ferredoxin:H2 oxidoreductase
KEGG:R12084 1.18.6.2 ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing, vanadium-dependent)
KEGG:R12754 1.17.98.- C00011 + C00282<=>C00058
BioCyc:RXN-16420 1.12.98.- Knallgas reaction
BioCyc:RXN0-7399 1.12.5.1 PROTON + Menaquinones + HYDROGEN-MOLECULE --> PROTON + Menaquinols
BioCyc:HYDROG-RXN 1.12.7.2 hydrogenase
BioCyc:RXN0-5255 2 PROTON + 2 E- --> HYDROGEN-MOLECULE
BioCyc:RXN0-5256 1.12.5.1 hydrogen:menaquinone oxidoreductase
BioCyc:TRANS-RXN0-610 diffusion of H2
BioCyc:FHLMULTI-RXN PROTON + FORMATE --> CARBON-DIOXIDE + HYDROGEN-MOLECULE
Rhea:RHEA:12117 1.12.99.6 H2 + A => AH2
Rhea:RHEA:12118 1.12.99.6 AH2 => H2 + A
Rhea:RHEA:12119 1.12.99.6 H2 + A <=> AH2
Rhea:RHEA:15646 1.19.6.1 N2 + 4 reduced [flavodoxin] + 16 ATP + 16 H2O => 4 oxidized [flavodoxin] + H2 + 2 NH4+ + 16 ADP + 16 phosphate + 18 H+
Rhea:RHEA:15647 1.19.6.1 4 oxidized [flavodoxin] + H2 + 2 NH4+ + 16 ADP + 16 phosphate + 18 H+ => N2 + 4 reduced [flavodoxin] + 16 ATP + 16 H2O
Rhea:RHEA:15648 1.19.6.1 N2 + 4 reduced [flavodoxin] + 16 ATP + 16 H2O <=> 4 oxidized [flavodoxin] + H2 + 2 NH4+ + 16 ADP + 16 phosphate + 18 H+