数据之源，洞见之始

11-demethylbrucine + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => β-colubrine + reduced [NADPH—hemoprotein reductase] + O₂

= [] + [] + H2O[H2O] + H+[H] + [] + [] + Oxygen[O2]

DB Links

• EC Number: 1.14.14.190
• Rhea: RHEA:80941

Alias

• [Rhea:RHEA:11777] octadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => (9Z)-octadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:11778] (9Z)-octadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O => octadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:11779] octadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> (9Z)-octadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:24321] an L-polyhomomethionine + reduced [NADPH—hemoprotein reductase] + O₂ => an L-N-hydroxypolyhomomethionine + oxidized [NADPH—hemoprotein reductase] + H₂O + 2 H⁺
• [Rhea:RHEA:24322] an L-N-hydroxypolyhomomethionine + oxidized [NADPH—hemoprotein reductase] + H₂O + 2 H⁺ => an L-polyhomomethionine + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:24323] an L-polyhomomethionine + reduced [NADPH—hemoprotein reductase] + O₂ <=> an L-N-hydroxypolyhomomethionine + oxidized [NADPH—hemoprotein reductase] + H₂O + 2 H⁺
• [Rhea:RHEA:38044] hexadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => (4Z)-hexadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:38045] (4Z)-hexadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O => hexadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:38046] hexadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> (4Z)-hexadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:46417] hexadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => (6Z)-hexadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:46418] (6Z)-hexadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O => hexadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:46419] hexadecanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> (6Z)-hexadecenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:46569] 5-hexenoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => 5-hexynoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:46570] 5-hexynoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O => 5-hexenoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:46571] 5-hexenoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> 5-hexynoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:46573] hexanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => 5-hexenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:46574] 5-hexenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O => hexanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:46575] hexanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> 5-hexenoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:51977] an L-N-hydroxypolyhomomethionine + reduced [NADPH—hemoprotein reductase] + O₂ => an L-N,N-dihydroxypolyhomomethionine + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:51978] an L-N,N-dihydroxypolyhomomethionine + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => an L-N-hydroxypolyhomomethionine + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:51979] an L-N-hydroxypolyhomomethionine + reduced [NADPH—hemoprotein reductase] + O₂ <=> an L-N,N-dihydroxypolyhomomethionine + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:51997] an (E)-ω-(methylsulfanyl)-alkanal oxime + reduced [NADPH—hemoprotein reductase] + O₂ => a (1E)-1-aci-nitro-ω-(methylsulfanyl)alkane + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:51998] a (1E)-1-aci-nitro-ω-(methylsulfanyl)alkane + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => an (E)-ω-(methylsulfanyl)-alkanal oxime + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:51999] an (E)-ω-(methylsulfanyl)-alkanal oxime + reduced [NADPH—hemoprotein reductase] + O₂ <=> a (1E)-1-aci-nitro-ω-(methylsulfanyl)alkane + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:52973] a C₂-C₈-saturated long-chain fatty acyl-[ACP] + reduced [flavodoxin] + O₂ => a (7S)-7-hydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + oxidized [flavodoxin] + H₂O + H⁺
• [Rhea:RHEA:52974] a (7S)-7-hydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + oxidized [flavodoxin] + H₂O + H⁺ => a C₂-C₈-saturated long-chain fatty acyl-[ACP] + reduced [flavodoxin] + O₂
• [Rhea:RHEA:52975] a C₂-C₈-saturated long-chain fatty acyl-[ACP] + reduced [flavodoxin] + O₂ <=> a (7S)-7-hydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + oxidized [flavodoxin] + H₂O + H⁺
• [Rhea:RHEA:52977] a (7S)-7-hydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + reduced [flavodoxin] + O₂ => a (7R,8R)-7,8-dihydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + oxidized [flavodoxin] + H₂O + H⁺
• [Rhea:RHEA:52978] a (7R,8R)-7,8-dihydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + oxidized [flavodoxin] + H₂O + H⁺ => a (7S)-7-hydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + reduced [flavodoxin] + O₂
• [Rhea:RHEA:52979] a (7S)-7-hydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + reduced [flavodoxin] + O₂ <=> a (7R,8R)-7,8-dihydroxy-C₂-C₈-saturated long-chain fatty acyl-[ACP] + oxidized [flavodoxin] + H₂O + H⁺
• [Rhea:RHEA:65809] decanoyl-[ACP] + 4 reduced [2Fe-2S]-[ferredoxin] + 2 O₂ + 4 H⁺ => dec-9-ynoyl-[ACP] + 4 oxidized [2Fe-2S]-[ferredoxin] + 4 H₂O
• [Rhea:RHEA:65810] dec-9-ynoyl-[ACP] + 4 oxidized [2Fe-2S]-[ferredoxin] + 4 H₂O => decanoyl-[ACP] + 4 reduced [2Fe-2S]-[ferredoxin] + 2 O₂ + 4 H⁺
• [Rhea:RHEA:65811] decanoyl-[ACP] + 4 reduced [2Fe-2S]-[ferredoxin] + 2 O₂ + 4 H⁺ <=> dec-9-ynoyl-[ACP] + 4 oxidized [2Fe-2S]-[ferredoxin] + 4 H₂O
• [Rhea:RHEA:65821] decanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => dec-9-enoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:65822] dec-9-enoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O => decanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:65823] decanoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> dec-9-enoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:65825] dec-9-enoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => dec-9-ynoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:65826] dec-9-ynoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O => dec-9-enoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:65827] dec-9-enoyl-[ACP] + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> dec-9-ynoyl-[ACP] + 2 oxidized [2Fe-2S]-[ferredoxin] + 2 H₂O
• [Rhea:RHEA:80940] β-colubrine + reduced [NADPH—hemoprotein reductase] + O₂ => 11-demethylbrucine + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:80941] 11-demethylbrucine + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => β-colubrine + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:80942] β-colubrine + reduced [NADPH—hemoprotein reductase] + O₂ <=> 11-demethylbrucine + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:81088] hancockiamide A + reduced [NADPH—hemoprotein reductase] + O₂ => hancockiamide G + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:81089] hancockiamide G + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺ => hancockiamide A + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:81090] hancockiamide A + reduced [NADPH—hemoprotein reductase] + O₂ <=> hancockiamide G + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:81132] hancockiamide D + reduced [NADPH—hemoprotein reductase] + O₂ => hancockiamide H + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:81133] hancockiamide H + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺ => hancockiamide D + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:81134] hancockiamide D + reduced [NADPH—hemoprotein reductase] + O₂ <=> hancockiamide H + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:81164] presphingofungin + 2 reduced [NADPH—hemoprotein reductase] + O₂ => sphingofungin B₁ + 2 oxidized [NADPH—hemoprotein reductase] + H₂O + 2 H⁺
• [Rhea:RHEA:81165] sphingofungin B₁ + 2 oxidized [NADPH—hemoprotein reductase] + H₂O + 2 H⁺ => presphingofungin + 2 reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:81166] presphingofungin + 2 reduced [NADPH—hemoprotein reductase] + O₂ <=> sphingofungin B₁ + 2 oxidized [NADPH—hemoprotein reductase] + H₂O + 2 H⁺
• [Rhea:RHEA:81184] a 2-methoxy-6-(all-trans-polyprenyl)phenol + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => a 2-methoxy-6-(all-trans-polyprenyl)benzene-1,4-diol + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O
• [Rhea:RHEA:81185] a 2-methoxy-6-(all-trans-polyprenyl)benzene-1,4-diol + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O => a 2-methoxy-6-(all-trans-polyprenyl)phenol + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:81186] a 2-methoxy-6-(all-trans-polyprenyl)phenol + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> a 2-methoxy-6-(all-trans-polyprenyl)benzene-1,4-diol + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O
• [Rhea:RHEA:81196] a 4-hydroxy-3-(all-trans-polyprenyl)benzoate + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => a 3,4-dihydroxy-5-(all-trans-polyprenyl)benzoate + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O
• [Rhea:RHEA:81197] a 3,4-dihydroxy-5-(all-trans-polyprenyl)benzoate + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O => a 4-hydroxy-3-(all-trans-polyprenyl)benzoate + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:81198] a 4-hydroxy-3-(all-trans-polyprenyl)benzoate + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> a 3,4-dihydroxy-5-(all-trans-polyprenyl)benzoate + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O
• [Rhea:RHEA:82040] 2'-N-hydroxynocardicin C + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ => 2'-N,N-dihydroxynocardicin C + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O
• [Rhea:RHEA:82041] 2'-N,N-dihydroxynocardicin C + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O => 2'-N-hydroxynocardicin C + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺
• [Rhea:RHEA:82042] 2'-N-hydroxynocardicin C + 2 reduced [2Fe-2S]-[ferredoxin] + O₂ + 2 H⁺ <=> 2'-N,N-dihydroxynocardicin C + 2 oxidized [2Fe-2S]-[ferredoxin] + H₂O
• [Rhea:RHEA:82276] N¹,N⁵,N¹⁰-tris[(E)-p-coumaroyl]spermidine + 3 reduced [NADPH—hemoprotein reductase] + 3 O₂ => N¹,N⁵,N¹⁰-tris[(E)-caffeoyl]spermidine + 3 oxidized [NADPH—hemoprotein reductase] + 3 H₂O + 3 H⁺
• [Rhea:RHEA:82277] N¹,N⁵,N¹⁰-tris[(E)-caffeoyl]spermidine + 3 oxidized [NADPH—hemoprotein reductase] + 3 H₂O + 3 H⁺ => N¹,N⁵,N¹⁰-tris[(E)-p-coumaroyl]spermidine + 3 reduced [NADPH—hemoprotein reductase] + 3 O₂
• [Rhea:RHEA:82278] N¹,N⁵,N¹⁰-tris[(E)-p-coumaroyl]spermidine + 3 reduced [NADPH—hemoprotein reductase] + 3 O₂ <=> N¹,N⁵,N¹⁰-tris[(E)-caffeoyl]spermidine + 3 oxidized [NADPH—hemoprotein reductase] + 3 H₂O + 3 H⁺
• [Rhea:RHEA:82280] N¹,N⁵,N¹⁰-tris[(E)-feruloyl]spermidine + 3 reduced [NADPH—hemoprotein reductase] + 3 O₂ => N¹,N⁵,N¹⁰-tris[(E)-5-hydroxyferuloyl]spermidine + 3 oxidized [NADPH—hemoprotein reductase] + 3 H₂O + 3 H⁺
• [Rhea:RHEA:82281] N¹,N⁵,N¹⁰-tris[(E)-5-hydroxyferuloyl]spermidine + 3 oxidized [NADPH—hemoprotein reductase] + 3 H₂O + 3 H⁺ => N¹,N⁵,N¹⁰-tris[(E)-feruloyl]spermidine + 3 reduced [NADPH—hemoprotein reductase] + 3 O₂
• [Rhea:RHEA:82282] N¹,N⁵,N¹⁰-tris[(E)-feruloyl]spermidine + 3 reduced [NADPH—hemoprotein reductase] + 3 O₂ <=> N¹,N⁵,N¹⁰-tris[(E)-5-hydroxyferuloyl]spermidine + 3 oxidized [NADPH—hemoprotein reductase] + 3 H₂O + 3 H⁺
• [Rhea:RHEA:82668] 5-hydroxy-4-(hydroxymethyl)-7-methoxy-6-methylphthalide + reduced [NADPH—hemoprotein reductase] + O₂ => cyclopolic acid + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82669] cyclopolic acid + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => 5-hydroxy-4-(hydroxymethyl)-7-methoxy-6-methylphthalide + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82670] 5-hydroxy-4-(hydroxymethyl)-7-methoxy-6-methylphthalide + reduced [NADPH—hemoprotein reductase] + O₂ <=> cyclopolic acid + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82712] 12-deshydroxyl okaramine E + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ => 3-desmethyl okaramine B + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 2 H⁺
• [Rhea:RHEA:82713] 3-desmethyl okaramine B + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 2 H⁺ => 12-deshydroxyl okaramine E + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂
• [Rhea:RHEA:82714] 12-deshydroxyl okaramine E + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ <=> 3-desmethyl okaramine B + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 2 H⁺
• [Rhea:RHEA:82728] isomotiol + reduced [NADPH—hemoprotein reductase] + O₂ => 2α-hydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82729] 2α-hydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => isomotiol + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82730] isomotiol + reduced [NADPH—hemoprotein reductase] + O₂ <=> 2α-hydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82748] 3-O-(β-D-glucopyranosyl)-isomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ => 2-deacetoxyfuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺
• [Rhea:RHEA:82749] 2-deacetoxyfuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺ => 3-O-(β-D-glucopyranosyl)-isomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂
• [Rhea:RHEA:82750] 3-O-(β-D-glucopyranosyl)-isomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ <=> 2-deacetoxyfuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺
• [Rhea:RHEA:82752] 3-O-(β-D-glucopyranosyl)-2α-hydroxyisomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ => 2-deacetylfuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺
• [Rhea:RHEA:82753] 2-deacetylfuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺ => 3-O-(β-D-glucopyranosyl)-2α-hydroxyisomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂
• [Rhea:RHEA:82754] 3-O-(β-D-glucopyranosyl)-2α-hydroxyisomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ <=> 2-deacetylfuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺
• [Rhea:RHEA:82756] 3-O-(β-D-glucopyranosyl)-2α-acetoxyisomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ => fuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺
• [Rhea:RHEA:82757] fuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺ => 3-O-(β-D-glucopyranosyl)-2α-acetoxyisomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂
• [Rhea:RHEA:82758] 3-O-(β-D-glucopyranosyl)-2α-acetoxyisomotiol + 2 reduced [NADPH—hemoprotein reductase] + 2 O₂ <=> fuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + 2 H₂O + 3 H⁺
• [Rhea:RHEA:82760] isomotiol + reduced [NADPH—hemoprotein reductase] + O₂ => 19β-hydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82761] 19β-hydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => isomotiol + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82762] isomotiol + reduced [NADPH—hemoprotein reductase] + O₂ <=> 19β-hydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82764] 2α-hydroxyisomotiol + reduced [NADPH—hemoprotein reductase] + O₂ => 2α,19β-dihydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82765] 2α,19β-dihydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => 2α-hydroxyisomotiol + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82766] 2α-hydroxyisomotiol + reduced [NADPH—hemoprotein reductase] + O₂ <=> 2α,19β-dihydroxyisomotiol + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82768] 2α,19β-dihydroxyisomotiol + reduced [NADPH—hemoprotein reductase] + O₂ => 2α-hydroxyismotiol-19-one + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:82769] 2α-hydroxyismotiol-19-one + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺ => 2α,19β-dihydroxyisomotiol + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82770] 2α,19β-dihydroxyisomotiol + reduced [NADPH—hemoprotein reductase] + O₂ <=> 2α-hydroxyismotiol-19-one + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:82772] 2α-hydroxyismotiol-19-one + 2 reduced [NADPH—hemoprotein reductase] + O₂ => 2-deacetyl,3-deglucopyranosyl-fuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + H₂O + 3 H⁺
• [Rhea:RHEA:82773] 2-deacetyl,3-deglucopyranosyl-fuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + H₂O + 3 H⁺ => 2α-hydroxyismotiol-19-one + 2 reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82774] 2α-hydroxyismotiol-19-one + 2 reduced [NADPH—hemoprotein reductase] + O₂ <=> 2-deacetyl,3-deglucopyranosyl-fuscoatroside + 2 oxidized [NADPH—hemoprotein reductase] + H₂O + 3 H⁺
• [Rhea:RHEA:82836] 2 campesine B + reduced [NADPH—hemoprotein reductase] + O₂ => campesine F + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:82837] campesine F + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺ => 2 campesine B + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82838] 2 campesine B + reduced [NADPH—hemoprotein reductase] + O₂ <=> campesine F + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:82844] campesine D + reduced [NADPH—hemoprotein reductase] + O₂ => campesine G + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:82845] campesine G + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺ => campesine D + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82846] campesine D + reduced [NADPH—hemoprotein reductase] + O₂ <=> campesine G + oxidized [NADPH—hemoprotein reductase] + 2 H₂O + H⁺
• [Rhea:RHEA:82868] wigandol + 4 reduced [NADPH—hemoprotein reductase] + 4 O₂ => arnebinol A + 4 oxidized [NADPH—hemoprotein reductase] + 6 H₂O + 4 H⁺
• [Rhea:RHEA:82869] arnebinol A + 4 oxidized [NADPH—hemoprotein reductase] + 6 H₂O + 4 H⁺ => wigandol + 4 reduced [NADPH—hemoprotein reductase] + 4 O₂
• [Rhea:RHEA:82870] wigandol + 4 reduced [NADPH—hemoprotein reductase] + 4 O₂ <=> arnebinol A + 4 oxidized [NADPH—hemoprotein reductase] + 6 H₂O + 4 H⁺
• [Rhea:RHEA:82872] arnebinol A + reduced [NADPH—hemoprotein reductase] + O₂ => clavilactone A + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺
• [Rhea:RHEA:82873] clavilactone A + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺ => arnebinol A + reduced [NADPH—hemoprotein reductase] + O₂
• [Rhea:RHEA:82874] arnebinol A + reduced [NADPH—hemoprotein reductase] + O₂ <=> clavilactone A + oxidized [NADPH—hemoprotein reductase] + H₂O + H⁺

Metabolites

Substrates

metabolite	compartment	Structure

Products

metabolite	compartment	Structure
Formula:	Cytoplasm
Formula:	Cytoplasm
H2O Formula: H2O	Cytoplasm
H+ Formula: H	Cytoplasm
Formula:	Cytoplasm
Formula:	Cytoplasm
Oxygen Formula: O2	Cytoplasm