ospF - Shigella dysenteriae
Phosphothreonine lyase OspF
> ospF - Shigella dysenteriae [Phosphothreonine lyase OspF]
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统计信息
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Metadata
Organism Source: 622 - Shigella dysenteriae
EC Number: 4.2.3.-
Cluster:
Registry Model:
Reactions
| reaction id | name | note |
|---|---|---|
| KEGG:R02011 | geranyl-diphosphate diphosphate-lyase (cyclizing, comphene-forming) | multi-step reaction |
| BioCyc:RXN-12987 | manool synthase | |
| BioCyc:RXN-8593 | FARNESYL-PP --> CPD-8792 + PPI | |
| BioCyc:RXN-8075 | GAP --> CPD-10807 + Pi | This reaction is a less-well known activity of |FRAME: EC-5.3.1.1| |CITS: [2021650]|. The product, |FRAME: CPD-10807|, spontaneously transforms into |FRAME: METHYL-GLYOXAL|.This elimination reaction is slow relative to the isomerization reaction and was detected only by chance in experiments where the substrate was incubated with large concentrations of the enzyme. However, since the enzyme is present at very high cellular concentrations, the elimination reaction could still generate significant concentrations of cellular methylglyoxal. |
| BioCyc:RXN-8577 | GERANYL-PP --> CPD-8771 + PPI | |
| BioCyc:RXN-8558 | FARNESYL-PP --> CPD-8751 + PPI | |
| BioCyc:RXN-13399 | FARNESYL-PP + WATER --> CPD-14374 + PPI | |
| BioCyc:RXN18C3-21 | GERANYLGERANYL-PP + WATER --> CPD-18855 + PPI | |
| BioCyc:RXN-10568 | CPD-11293 --> --beta-santalene + PPI | |
| BioCyc:RXN-12984 | sclarene synthase | Requires Mg2+ for activity. |
| BioCyc:RXN-8590 | FARNESYL-PP --> CPD-8789 + PPI | |
| BioCyc:RXN-8555 | FARNESYL-PP --> CPD-8748 + PPI | |
| BioCyc:RXN-13373 | FARNESYL-PP --> PPI + CPD-14342 | |
| BioCyc:RXN-8571 | FARNESYL-PP + WATER --> CPD-8761 + PPI | |
| BioCyc:RXN-8423 | FARNESYL-PP --> CPD-8240 + PPI | Arabidopsis thaliana has at least 32 genes with sequence similarity to known terpene synthase (TPS) genes |CITS: [12207221]|,each of which are expressed in one or more organs |CITS: [16297850]|.Terpene synthase genes expressed predominantly in flowers have been further investigated for reactions catalyzed.In flowers, β-acoradiene is produced from farnesyl diphosphate by the TPS encoded by AT5G44630|CITS: [15918888]|.Volatile terpenoids have been identified in floral emissions of Arabidopsis thalianaand associated with pollinator attraction |CITS: [11960742]|,which may serve to produce the limited amount of outcrossing which has been observedin this self-compatible species |CITS: [Abbott89]|.However, production of floral volatile terpenes may serve other functions,such as protection against oxidative stress |CITS: [11743121]| or defense against pathogens |CITS: [10515903]|.Alternatively, this may be a trait that has not yet been eliminated by drift or selection after A. thalianadiverged in this clade containing a number of related self-incompatible species |CITS: [11018155]|. |
| BioCyc:RXN-12999 | syn-copalol synthase | |
| BioCyc:RXN-8622 | FARNESYL-PP --> Sesquisabinene + PPI | |
| BioCyc:RXN-8548 | FARNESYL-PP --> CPD-8739 + PPI | |
| BioCyc:RXN-8419 | FARNESYL-PP --> CPD-8237 + PPI | Arabidopsis thaliana has at least 32 genes with sequence similarity to known terpene synthase (TPS) genes |CITS: [12207221]|,each of which are expressed in one or more organs |CITS: [16297850]|.Terpene synthase genes expressed predominantly in flowers have been further investigated for reactions catalyzed.In flowers, isobazzanene is produced from farnesyl diphosphate by the TPS encoded by AT5G44630|CITS: [15918888]|.Volatile terpenoids have been identified in floral emissions of Arabidopsis thalianaand associated with pollinator attraction |CITS: [11960742]|,which may serve to produce the limited amount of outcrossing which has been observedin this self-compatible species |CITS: [Abbott89]|.However, production of floral volatile terpenes may serve other functions,such as protection against oxidative stress |CITS: [11743121]| or defense against pathogens |CITS: [10515903]|.Alternatively, this may be a trait that has not yet been eliminated by drift or selection after A. thalianadiverged in this clade containing a number of related self-incompatible species |CITS: [11018155]|. |
| BioCyc:RXN-10603 | α-patchoulene synthase | |
| BioCyc:RXN-8597 | FARNESYL-PP --> CPD-8796 + PPI | |
| BioCyc:RXN-8545 | FARNESYL-PP --> CPD-8734 + PPI | |
| BioCyc:RXN-5103 | GERANYL-PP --> CPD-4893 + PPI | |
| BioCyc:RXN-12988 | 13-epi-manool synthase | |
| BioCyc:RXN-19537 | PRPP + WATER --> RIBOSE-5P + PPI | |
| BioCyc:RXN-8594 | FARNESYL-PP --> CPD-8793 + PPI | |
| BioCyc:RXN-8559 | FARNESYL-PP --> CPD-8752 + PPI | |
| BioCyc:RXN-8542 | FARNESYL-PP --> CPD-8731 + PPI | |
| BioCyc:RXN-13409 | FARNESYL-PP --> CPD-14376 + PPI | |
| BioCyc:RXN-12985 | (Z)-biformene synthase | Requires Mg2+ for activity. |
| BioCyc:RXN-8591 | FARNESYL-PP --> CPD-8790 + PPI | |
| BioCyc:RXN-8575 | GERANYL-PP --> CPD-8765 + PPI | |
| BioCyc:RXN-12835 | isopimara-8,15-diene synthase | The enzyme from rice (|FRAME: TAX-4530|), expressed in Escherichia coli, produces exclusively |FRAME: CPD-13869| from |FRAME: CPD-4750|. With |FRAME: CPD-8719| as substrate |FRAME: CPD-9907| is produced (c.f. |FRAME: RXN-9291 "EC 4.2.3.34, stemod-13(17)-ene synthase"|) |
| BioCyc:RXN-8931 | FARNESYL-PP --> CPD-9338 + PPI | |
| BioCyc:RXN-5122 | GERANYL-PP --> CPD-4901 + PPI | |
| BioCyc:RXN-12117 | CPD-9444 --> CPD-13069 + PPI | This enzyme, characterized from tobacco, is capable of catalysing both cisoid and transoid cyclization pathways |CITS: [20175559]|. When acting on (2E,6E)-farnesyl diphosphate, the enzyme produces |FRAME: ARISTOLOCHENE| as the major product, via the transoid pathway (|FRAME: ARISTOLOCHENE-SYNTHASE-RXN "EC 4.2.3.9, aristolochene synthase"|). When acting on (2Z,6E)-farnesyl-diphosphate, the enzyme produces several products via the cisoid pathway, the major ones being |FRAME: CPD-13069| (44%), |FRAME: CPD-8776| (21.5%) (cf. |FRAME: RXN-8585 "EC 4.2.3.ao"|) and |FRAME: CPD-11392| (15.5%) (cf. |FRAME: RXN-10598 "EC 4.2.3.ap"|) |CITS: [20201526]|. |
| BioCyc:RXN-14125 | 4-PHOSPHONOOXY-THREONINE + WATER --> CPD0-2189 + Pi | |
| BioCyc:RXN-18523 | ALL-TRANS-PENTAPRENYL-DIPHOSPHATE + CPD-9546 --> CPD-19846 + PPI | This is a hypothetical reaction in the biosynthesis of |FRAME: CPD-7323|. According to the proposed model, the polyprenyl side-chain of methanophenazine is transferred from |FRAME: ALL-TRANS-PENTAPRENYL-DIPHOSPHATE| (GFPP) to |FRAME: CPD-9546|, followed by the selective reduction of its double bond at position 2 |CITS: [9555882]|. |
| BioCyc:RXN-13522 | seychellene synthase | |
| BioCyc:RXN-8606 | FARNESYL-PP --> CPD-8812 + PPI | |
| BioCyc:RXN-13000 | (13S)-vitexifolin A synthase | |
| BioCyc:RXN-8602 | FARNESYL-PP --> CPD-8802 + PPI | |
| BioCyc:RXN-8585 | (-)-α-cedrene synthase | This enzyme, characterized from tobacco, is capable of catalysing both cisoid and transoid cyclization pathways |CITS: [20175559]|. When acting on (2E,6E)-farnesyl diphosphate, the enzyme produces |FRAME: ARISTOLOCHENE| as the major product, via the transoid pathway (|FRAME: ARISTOLOCHENE-SYNTHASE-RXN "EC 4.2.3.9, aristolochene synthase"|). When acting on (2Z,6E)-farnesyl-diphosphate, the enzyme produces several products via the cisoid pathway, the major ones being |FRAME: CPD-13069| (44%) (cf. |FRAME: RXN-12117 "EC 4.2.3.m"|), |FRAME: CPD-8776| (21.5%) and |FRAME: CPD-11392| (15.5%) (cf. |FRAME: RXN-10598 "EC 4.2.3.ap"|) |CITS: [20201526]|. |
| BioCyc:RXN-8421 | FARNESYL-PP --> CPD-8238 + PPI | Arabidopsis thaliana has at least 32 genes with sequence similarity to known terpene synthase (TPS) genes |CITS: [12207221]|,each of which are expressed in one or more organs |CITS: [16297850]|.Terpene synthase genes expressed predominantly in flowers have been further investigated for reactions catalyzed.In flowers, (+)-β-barbatene is produced from farnesyl diphosphate by the TPS encoded by AT5G44630|CITS: [15918888]|.Volatile terpenoids have been identified in floral emissions of Arabidopsis thalianaand associated with pollinator attraction |CITS: [11960742]|,which may serve to produce the limited amount of outcrossing which has been observedin this self-compatible species |CITS: [Abbott89]|.However, production of floral volatile terpenes may serve other functions,such as protection against oxidative stress |CITS: [11743121]| or defense against pathogens |CITS: [10515903]|.Alternatively, this may be a trait that has not yet been eliminated by drift or selection after A. thalianadiverged in this clade containing a number of related self-incompatible species |CITS: [11018155]|. |
| BioCyc:RXN18C3-50 | labdenediol synthase | |
| BioCyc:RXN-8513 | CPD-4750 --> CPD-8697 + PPI | |
| BioCyc:RXN-5105 | GERANYL-PP --> CPD-4894 + PPI | |
| BioCyc:RXN-10601 | β-patchoulene synthase | |
| BioCyc:RXN-17085 | GERANYLGERANYL-PP --> CPD-18470 + PPI | |
| BioCyc:RXN-8595 | FARNESYL-PP --> CPD-8794 + PPI | |
| BioCyc:RXN-8560 | FARNESYL-PP --> CPD-8753 + PPI | |
| BioCyc:RXN-8543 | FARNESYL-PP --> CPD-8732 + PPI | |
| BioCyc:RXN-8431 | FARNESYL-PP --> CPD-8248 + PPI | Arabidopsis thaliana has at least 32 genes with sequence similarity to known terpene synthase (TPS) genes |CITS: [12207221]|,each of which are expressed in one or more organs |CITS: [16297850]|.Terpene synthase genes expressed predominantly in flowers have been further investigated for reactions catalyzed.In flowers, δ-cuprenene is produced from farnesyl diphosphate by the TPS encoded by AT5G44630|CITS: [15918888]|.Volatile terpenoids have been identified in floral emissions of Arabidopsis thalianaand associated with pollinator attraction |CITS: [11960742]|,which may serve to produce the limited amount of outcrossing which has been observedin this self-compatible species |CITS: [Abbott89]|.However, production of floral volatile terpenes may serve other functions,such as protection against oxidative stress |CITS: [11743121]| or defense against pathogens |CITS: [10515903]|.Alternatively, this may be a trait that has not yet been eliminated by drift or selection after A. thalianadiverged in this clade containing a number of related self-incompatible species |CITS: [11018155]|. |
| BioCyc:RXN-18791 | FARNESYL-PP --> CPD-20084 + PPI | |
| BioCyc:RXN-10598 | FARNESYL-PP --> PPI + CPD-11392 | This enzyme, characterized from tobacco, is capable of catalysing both cisoid and transoid cyclization pathways |CITS: [20175559]|. When acting on (2E,6E)-farnesyl diphosphate, the enzyme produces |FRAME: ARISTOLOCHENE| as the major product, via the transoid pathway (|FRAME: ARISTOLOCHENE-SYNTHASE-RXN "EC 4.2.3.9, aristolochene synthase"|). When acting on (2Z,6E)-farnesyl-diphosphate, the enzyme produces several products via the cisoid pathway, the major ones being |FRAME: CPD-13069| (44%) (cf. |FRAME: RXN-12117 "EC 4.2.3.m"|), |FRAME: CPD-8776| (21.5%) (cf. |FRAME: RXN-8585 "EC 4.2.3.ao"|) and |FRAME: CPD-11392| (15.5%) |CITS: [20201526]|. |
| BioCyc:RXN-8557 | FARNESYL-PP --> CPD-8750 + PPI | |
| BioCyc:RXN18C3-20 | GERANYLGERANYL-PP + WATER --> CPD-18854 + PPI | |
| BioCyc:RXN-8428 | FARNESYL-PP --> CPD-8245 + PPI | Arabidopsis thaliana has at least 32 genes with sequence similarity to known terpene synthase (TPS) genes |CITS: [12207221]|,each of which are expressed in one or more organs |CITS: [16297850]|.Terpene synthase genes expressed predominantly in flowers have been further investigated for reactions catalyzed.In flowers, α-chamigrene is produced from farnesyl diphosphate by the TPS encoded by AT5G44630|CITS: [15918888]|.Volatile terpenoids have been identified in floral emissions of Arabidopsis thalianaand associated with pollinator attraction |CITS: [11960742]|,which may serve to produce the limited amount of outcrossing which has been observedin this self-compatible species |CITS: [Abbott89]|.However, production of floral volatile terpenes may serve other functions,such as protection against oxidative stress |CITS: [11743121]| or defense against pathogens |CITS: [10515903]|.Alternatively, this may be a trait that has not yet been eliminated by drift or selection after A. thalianadiverged in this clade containing a number of related self-incompatible species |CITS: [11018155]|. |
| BioCyc:RXN-5123 | GERANYL-PP --> CPD-4903 + PPI | |
| BioCyc:RXN-8607 | FARNESYL-PP --> CPD-8811 + PPI | |
| BioCyc:RXN-8589 | FARNESYL-PP --> CPD-8788 + PPI | |
| BioCyc:RXN-8573 | FARNESYL-PP --> CPD-8763 + PPI | |
| BioCyc:RXN-8554 | FARNESYL-PP --> CPD-8747 + PPI | |
| BioCyc:RXN-18852 | FARNESYL-PP --> CPD-20214 + PPI | |
| BioCyc:RXN-8603 | FARNESYL-PP --> CPD-8801 + PPI | |
| BioCyc:RXN-8586 | FARNESYL-PP --> CPD-8777 + PPI | |
| BioCyc:RXN-12996 | ent-manool synthase | |
| BioCyc:RXN-8600 | FARNESYL-PP --> CPD-8799 + PPI | |
| BioCyc:RXN-10602 | γ-patchoulene synthase | |
| BioCyc:RXN-8544 | FARNESYL-PP --> CPD-8733 + PPI | |
| BioCyc:RXN-8432 | FARNESYL-PP --> CPD-8232 + PPI | Arabidopsis thaliana has at least 32 genes with sequence similarity to known terpene synthase (TPS) genes |CITS: [12207221]|,each of which are expressed in one or more organs |CITS: [16297850]|.Terpene synthase genes expressed predominantly in flowers have been further investigated for reactions catalyzed.In flowers, β-elemene is produced from farnesyl diphosphate by the TPS encoded by AT5G23960|CITS: [12566586],[15918888]|.Volatile terpenoids have been identified in floral emissions of Arabidopsis thalianaand associated with pollinator attraction |CITS: [11960742]|,which may serve to produce the limited amount of outcrossing which has been observedin this self-compatible species |CITS: [Abbott89]|.However, production of floral volatile terpenes may serve other functions,such as protection against oxidative stress |CITS: [11743121]| or defense against pathogens |CITS: [10515903]|.Alternatively, this may be a trait that has not yet been eliminated by drift or selection after A. thalianadiverged in this clade containing a number of related self-incompatible species |CITS: [11018155]|. |
Pathways
| pathway id | name |
|---|