oleoresin monoterpene volatiles biosynthesis

Martin DM, Fäldt J, Bohlmann J. Functional characterization of nine Norway Spruce TPS genes and evolution of gymnosperm terpene synthases of the TPS-d subfamily. Plant Physiol. 2004 Aug;135(4):1908–27. PMID: 15310829; PMCID: PMC520763.; Trapp S, Croteau R. DEFENSIVE RESIN BIOSYNTHESIS IN CONIFERS. Annu. Rev. Plant. Physiol. Plant. Mol. Biol. 2001 Jun;52(1):689–724. doi: 10.1146/annurev.arplant.52.1.689.; Phillips MA, Savage TJ, Croteau R. Monoterpene Synthases of Loblolly Pine (Pinus taeda) Produce Pinene Isomers and Enantiomers. Archives of Biochemistry and Biophysics. 1999 Dec;372(1):197–204. doi: 10.1006/abbi.1999.1467.; Bohlmann J, Phillips M, Ramachandiran V, Katoh S, Croteau R. cDNA Cloning, Characterization, and Functional Expression of Four New Monoterpene Synthase Members of the Tpsd Gene Family from Grand Fir (Abies grandis). Archives of Biochemistry and Biophysics. 1999 Aug;368(2):232–43. doi: 10.1006/abbi.1999.1332.; Phillips, Croteau. Resin-based defenses in conifers. Trends Plant Sci. 1999 May;4(5):184–90. doi: 10.1016/s1360-1385(99)01401-6. PMID: 10322558.; Steele CL, Crock J, Bohlmann J, Croteau R. Sesquiterpene synthases from grand fir (Abies grandis). Comparison of constitutive and wound-induced activities, and cDNA isolation, characterization, and bacterial expression of delta-selinene synthase and gamma-humulene synthase. J Biol Chem. 1998 Jan 23;273(4):2078–89. doi: 10.1074/jbc.273.4.2078. PMID: 9442047.

Metabolites

(-)-alpha-Pinene

Formula: C10H16 (136.1251936)

CAS ID: 7785-26-4

(-)-beta-Phellandrene

Formula: C10H16 (136.1251936)

CAS ID: 6153-17-9

(-)-beta-Pinene

Formula: C10H16 (136.1251936)

CAS ID: 18172-67-3

(-)-Camphene

Formula: C10H16 (136.1251936)

CAS ID: 5794-04-7

(+)-3-Carene

Formula: C10H16 (136.1251936)

CAS ID: 498-15-7

(S)-Limonene

Formula: C10H16 (136.1251936)

CAS ID: 5989-54-8

Diphosphate

Formula: H4P2O7 (177.9432294)

CAS ID: 2466-09-3

Myrcene

Formula: C10H16 (136.1251936)

CAS ID: 123-35-3

Tricyclene

Formula: C10H16 (136.1251936)

CAS ID: 508-32-7



Enzyme

EC Number name full name note
4.2.3.107 (+)-car-3-ene synthase geranyl-diphosphate diphosphate-lyase [cyclizing, (+)-car-3-ene-forming]
4.2.3.113 terpinolene synthase geranyl-diphosphate diphosphate-lyase (cyclizing, terpinolene-forming)
4.2.3.117 (-)-camphene synthase geranyl-diphosphate diphosphate-lyase [cyclizing, (-)-camphene-forming]
4.2.3.119 (-)-alpha-pinene synthase geranyl-diphosphate diphosphate-lyase [cyclizing, (-)-alpha-pinene-forming]
4.2.3.120 (-)-beta-pinene synthase geranyl-diphosphate diphosphate-lyase [cyclizing, (-)-beta-pinene-forming]
4.2.3.15 myrcene synthase geranyl-diphosphate diphosphate-lyase (myrcene-forming)
4.2.3.16 (4S)-limonene synthase geranyl-diphosphate diphosphate-lyase [cyclizing; (-)-(4S)-limonene-forming]
4.2.3.52 (4S)-beta-phellandrene synthase (geranyl-diphosphate-cyclizing) geranyl-diphosphate diphosphate-lyase [cyclizing; (4S)-beta-phellandrene-forming]
4.2.3.56 gamma-humulene synthase (2E,6E)-farnesyl-diphosphate diphosphate-lyase (gamma-humulene-forming)
4.2.3.71 (E,E)-germacrene B synthase (2E,6E)-farnesyl-diphosphate diphosphate-lyase [(E,E)-germacrene-B-forming]
4.2.3.76 (+)-delta-selinene synthase (2E,6E)-farnesyl-diphosphate diphosphate-lyase [(+)-delta-selinene-forming]


Proteins

Protein ID name full name