Premithramycin A2' (BioCAD00000016618)

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Metabolite Card

Formula: C33H38O15 (674.2211)
SMILES: CO[C@H]1[C@@H]2Cc3cc4cc(O)cc(O)c4c(O)c3C(=O)[C@]2(O[C@H]2C[C@@H](O[C@H]3C[C@@H](O)[C@@H](O)[C@@H](C)O3)[C@H](O)[C@@H](C)O2)C(=O)C(C(C)=O)=C1O

Synonyms [en]

Premithramycin A2'; premithramycin A2; (1S,4aS,12aS)-3-acetyl-2,6,7,9-tetrahydroxy-1-methoxy-4,5-dioxo-1,5,12,12a-tetrahydrotetracen-4a(4H)-yl 2,6-dideoxy-beta-D-lyxo-hexopyranosyl-(1->3)-2,6-dideoxy-beta-D-arabino-hexopyranoside; (1S,4aR,12aS)-3-acetyl-4a-[(2S,4R,5R,6R)-4-[(2S,4R,5R,6R)-4,5-dihydroxy-6-methyl-tetrahydropyran-2-yl]oxy-5-hydroxy-6-methyl-tetrahydropyran-2-yl]oxy-4,6,7,9-tetrahydroxy-1-methoxy-12,12a-dihydro-1H-tetracene-2,5-dione; AC1L9F7R; (1S,4aR,12aS)-3-acetyl-4a-[(2S,4R,5R,6R)-4-[(2S,4R,5R,6R)-4,5-dihydroxy-6-methyloxan-2-yl]oxy-5-hydroxy-6-methyloxan-2-yl]oxy-4,6,7,9-tetrahydroxy-1-methoxy-12,12a-dihydro-1H-tetracene-2,5-dione

Reviewed

Last reviewed on 2024-06-28.

Cite this Page

Premithramycin A2'. 数据之源，洞见之始. SMRUCC genomics institute, a synthetic life researcher from China. https://biocad_registry.innovation.ac.cn/s/(-)-arctiin (retrieved 2026-01-03) (CAD Registry RN: BioCAD00000016618). Licensed under the Attribution-Noncommercial 4.0 International License (CC BY-NC 4.0).

Note

A tetracenomycin that is an intermediate in the biosynthesis of the antitumour drug mithramycin by Streptomyces argillaceus." []

Entity Information

DBLinks

Other DBLinks
  • PubChem: 443797
  • ChEBI: ChEBI:32047
  • KEGG: C12385
  • BioCyc: CPD-14347
  • RefMet: RM0157188
  • Metlin: METLIN_63781

Class / Ontology

Metabolic Network
ID EC Number Name
KEGG:R06717 2.4.1.- dTDP-D-oliose:premithramycin-A1 D-oliosyltransferase
KEGG:R06718 C12385 + C12444<=>C12386 + C00363
BioCyc:RXN-13376 2.4.1.- CPD-13966 + CPD-13956 --> CPD-14347 + TDP + PROTON
BioCyc:RXN-13377 2.4.1.- CPD-14347 + CPD-13957 --> CPD-14348 + TDP + PROTON
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Organism Source

Taxonomy Source

Pathway Synthetic

pathway id name
BioCyc:META_PWY-7045 mithramycin biosynthesis
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